The autopore iv 9500 series of mercury porosimeters from micromeritics enable the user to calculate numerous sample properties. Autopore iv 9500, from micromeritics, and the solid density, determined by helium pycnometry at 35 c in an accupyc 30 from micromeritics. Synthesis of macroporous polystyrenedivinyl benzene. The autopore v series mercury porosimeters can determine a broader pore size distribution. Implication and evaluation of micromeritics in formulation by. Autopore iv 9500 is a shareware software in the category miscellaneous developed by autopore iv 9500. Autopore iv series porosimeters pharmaceutical online. Material characterization the archimedes method was used to measure the bulk densities of the porous.
Pdf using xray computed tomography in pore structure. Micromeritics autopore v series mercury intrusion porosimeters are available in two models to suit the needs of research and quality assurance laboratories. An mip instrument autopore iv 9500, micromeritics was used to measure the pore size distributions. Sic conversion coating prepared from silicagraphite reaction. Micromeritics autopore iv 9500 series characterizes a materials porosity by applying various levels of pressure to a sample immersed in mercury. Changes in physicochemical and biological properties of. Autopore iv 9500 nonwetting fluid mercury intrusion device, by pressure, for pore size distribution determining in solid porous sample. Autopore iv 9500 series measures sample porosity laboratory. Finally, pore structure was evaluated by mercury intrusion porosimetry. Other collected fragments were were used for sem tests. Autopore iv 9500, micromeritics, norcross, ga, usa, in the pressure range of 0. The raman spectra were acquired on a jobinyvon labram hr 800 microraman system.
The pressure applied by the intrusion porosimeter ranged from 0 to 200 mpa in step mode. The bulk density was measured by the archimedes method in water medium, as shown in equation 1 14. Mercury intrusion porosimetry mip is a powerful technique utilized for the evaluation of porosity, pore size distribution, and pore volume among others to characterize a wide variety of solid and powder materials. Mercury intrusion porosimeter scientific and technical. The apparent porosity of the specimens was measured by the archimedes method. Micromeritics also offers a large selection of penetrometer bulbs, volumes, stems, and closures designed to fit most sample forms. The autopore iv can accurately collect the data that provide the basis for. It was initially added to our database on 07082008. The 9505 has four low and two highpressure chambers. The autopore v series porosimeters from micromeritics use the mercury porosimetry analysis method, in which mercury is introduced into a porous structure under closely monitored pressures. The open porosity and pore size were measured using a mercury porosimetry autopore iv 9500, micromeritics, usa. Passive human body cooling a wearable polyethylenepolyamide. A choice of correction routine for baseline automatic, differential, or manual produces greater.
This instrument also features enhanced safety features and offers new data reduction and reporting choices that provide more information about pore geometry and the fluid transport characteristics of your material. Fabrication steps of porous al2o3 ceramics by gelcasting, a al2o3 suspension. The autopore v series mercury porosimeters can determine a broader pore size distribution more quickly and accurately than other methods. The autopore iv software allows you to enter the precise. Autopore iv 9500 series specifications general low pressure.
Dec 30, 2017 micromeritics autopore iv 9500 series characterizes a materials porosity by applying various levels of pressure to a sample immersed in mercury. The autopore iv 9500 has two low and one highpressure chamber. The aim of the present study was to investigate asiii oxidation and adsorption on the surface of hybrid anion exchangers containing cuiifeiii b. This document will provide a detailed operation procedure of the micromeritics autopore iv po. Speciicaions autopore iv 9500 series micromeritics. Bap is found to be much closer to the formation rate of human bones 1,2. Fabrication of porous al2o3 ceramics with submicronsized. The autopore iv uses pressurized mercury to measure the pore sizes in materials. Mercury intrusion pressure is raised automatically, up to 220 mpa, and intruded volume into sample is related with porosity determination. The unit of particle size used in the micrometer m, micron and equal to 106 m.
Overview micromeritics autopore iv 9500 series characterizes a materials porosity by applying various levels of pressure to a sample immersed in mercury. Abele1,2 1 institute of production management, technology and machine tools ptw, technische universitat darmstadt, germany. The apparent density of the biochar evaluated in this work is large compared to other gac developed from the same precursor by co 2 activation due to the narrower pore size distribution of the biochar. The autopore iv 9500 has two low pressure ports and one high pressure port. Related content from micromeritics instrument corporation. Tunable and weakly negative permittivity in carbonsilicon. The autopore iv series is available in four models to best match the needs of individual quality assurance and research labs. In order to measure porosity in the range from 1 mm down to 2 nm, a micromeritics autopore iv 9500 porosimeter micromeritics instrument corporation, norcross ga, us was used. Both models can reach a maximum pressure of 33,000 psia and measure pore diameters ranging from 360.
Autopore iv series mercury porosimeter 9500 and 9510. This is called mercury porosimetry, or often, mercury intrusion. Fabrication of icetemplated tubes by rotational freezing. Mercury intrusion porosimetry mip is a powerful technique utilized for the evaluation of porosity, pore size. Experimental and simulation study of adsorption in. Mechanical properties of icetemplated tubes were characterized by two different tests. Sample data outputs from analyses including bet specific surface area. The autopore iv 9605 series has 4 lowpressure ports and 2 highpressure ports for analysis at up to 33,000psia. Three independently measured density values are average out and reported as the density of the sintered sample.
Mercury porosimetry is a fast and precise technique for porosity characterization with a broad measurement range, suitable for a wide range of sample types. Introduction the science and technology of small particles was given by the name micromeritics by dalla valle micromeritics is the science and technology of small particles. The instrument, known as a porosimeter, employs a pressurized chamber to force mercury to intrude into the voids in a porous. Specifications autopore iv 9500 series micromeritics. Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate numerous sample properties. For determining the exact contact angle, micromeritics offers. This measurement is based on the nonwetting behavior of mercury to most materials and takes advantage of the relationship of pore size and the intrusion pressure. These include pore size distributions, total pore volume, total pore surface area, median pore diameter and sample densities bulk and skeletal. Micromeritics instrument corporation autopore iv 9500 v1.
Speciicaions autopore iv 9500 series low pressure measurement 0 to 50 psia 345 kpa pore diameter range 360 to 3. Model 9505 from atmospheric pressure to 33,000 psia 228 mpa model 9520 from atmospheric pressure to 60,000 psia 414 mpa pore diameter. Analysis of particle size distribution the particle size distribution and the average diameter were measured by laser diffractometry using mastersizer 2000e. Our latest offering, the autopore iv series of mercury porosimeters, provides the same highquality analysis data as expected from other micromeritics products and, in addition, comes with enhanced data reduction and reporting packages, faster pressure ramp rates, a more flexible and controllable vacuum system, and a redesign of both the low. Autopore v series mercury porosimeters pharmaceutical online. Agilent e4991a precision impedance analyzer combined with 16453a dielectric test. Micromeritics autopore iv 9500 particle technology labs. Micromeritics autopore iv porosimeters 9500 series. Mercury intrusion porosimetry mip using micromeritics autopore iv 9500, micromeritics instrument corp. Autopore iv 9500 runs on the following operating systems. Autopore iv series 9500 and 9510 mercury porosimetery.
Microstructure and diffraction patterns of the fragment samples separated from coating layer were analyzed by 200 kv fetem field emission transmission electron microscope, tecnai g2 f20. Pdf oxidation resistance and wetting behavior of mgoc. All the experiments were conducted with a universal testing machine shimadzu model agsx, kyoto. Micromeritics also offers a large selection of penetrometer bulbs, volumes, stems, and closures designed to fit most sample forms, shapes, porosity, and quantity. It is the science and technology of small particles. Micromeritics autopore iv 9500 series characterizes a materials. The porosity and pore size distribution were analyzed by using mercury porosimetry autopore iv 9500, micromeritics, shang hai, china. The pressure required to intrude mercury into the samples pores is inversely proportional to the size of the pores. Autopore iv 9500 has not been rated by our users yet. Experiments were conducted in accordance with the protocol given in the autopore iv 9500 operators manual.
Mercury intrusion porosimetry particle technology labs. The mercury porosimetry analysis technique is based on the intrusion of mercury into a porous structure under stringently controlled pressures. Micromeritics mercury porosimeter autopore iv created date. Autopore iv 9500 mercury porosimetry micromeritics, usa. Threedimensional porous coppergraphene heterostructures. Using xray computed tomography in pore structure characterization for a berea sandstone. The pore size distribution of the sic coating was analyzed by mercury intrusion porosimetry autopore iv 9500 micromeritics instrument. Click here to download the autopore iv series porosimeters brochure in pdf. The latest version of autopore iv 9500 is currently unknown. Micromeritics autopore iv 9500 series characterizes a materials porosity by. Autopore iv 9500, micromeritics, norcross, ga, usa. As particle size decreases v, area increases 20140223 3 faculty of pharmacy, omer almukhtar university, tobruk, libya. Porosity was evaluated by using the settime equilibrium 10 s mode between the pressure limits of 0.
High sulfate attack resistance of reinforced concrete. The bulk density was measured by the archimedes method in. Paper open access workability and mechanical property of. Effects of the molding method and blank size of green body on. Hydration development and thermal performance of calcium. Micromeritics, auto pore iii, mercury intrusion porosimeter. The relationship is provided by the washburn equation equation s1 s1 2 c o s p r.
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